Bis(mandelato)borate: an effective, inexpensive spiroborate anion for chiral resolution.
نویسندگان
چکیده
Bis(mandelato)borate [B(Man)2](-) (R- or S-) anions are simply prepared and appear widely effective for resolution of racemic cations. Three examples demonstrate their scope; the alkaloid tetrahydropalmatine (THP), 1,2-diaminopropane (1,2-dap) and the metal-organic complex [Co(phen)3](3+) are readily resolved, either by a facile one-pot procedure, or via counter-ion metathesis.
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 87 شماره
صفحات -
تاریخ انتشار 2015